| dc.identifier.uri | http://hdl.handle.net/1951/59644 | |
| dc.identifier.uri | http://hdl.handle.net/11401/71217 | |
| dc.description.sponsorship | This work is sponsored by the Stony Brook University Graduate School in compliance with the requirements for completion of degree. | en_US |
| dc.format | Monograph | |
| dc.format.medium | Electronic Resource | en_US |
| dc.language.iso | en_US | |
| dc.publisher | The Graduate School, Stony Brook University: Stony Brook, NY. | |
| dc.type | Thesis | |
| dcterms.abstract | Since Shirakawa et
al. discovered the promising electrical conductivity of polyacetylene in the 1970s, polyacetylenes and their
analogous have been extensively explored as advanced materials. Among them, polytriacetylenes are a new class of
conjugated polymers that can only be achieved by topochemical polymerization. Theoretically, topochemically
polymerizing the triacetylene monomers is the most direct route to get polytriacetylene. However, the challenge in
1,6 polymerization is to get the suitable molecular spacing for the topochemical reaction. Host-guest strategy was
developed to achieve the specific spacing suitable for topochemical polymerizations, such as 1,4 and 1,6-
polymerizations. After optimizing the previous synthesis route and crystal growing method, a quality co-crystals of
3-((3-(pyridin-4-yl)propyl)amino)cyclohex-2-enone and dodeca-4,6,8-triynedioic acid was successfully prepared. The
co-crystal, with repeat distance of 7.25 ? , underwent a 100% polymerization at 115 degrees C over 19days. X-ray
diffraction was used to characterize all monomer and polymer crystals. Another attempt has been made to design and
synthesize a triacetylenes that assembled due to pi-pi interaction. This pyridyl-substituted triacetylene was
successfully synthesized in a five-step route. X-ray diffraction was utilized to characterize the single crystal of
octa-2,4,6-triyne-1,8-diyl dinicotinate which indicated the repeat distance of 7.408 ? . This value meets the ideal
requirement for 1,6- polymerization. | |
| dcterms.available | 2013-05-22T17:34:30Z | |
| dcterms.available | 2015-04-24T14:46:32Z | |
| dcterms.contributor | Lauher, Joseph W., Fowler,
Frank W. | en_US |
| dcterms.creator | Fan, Zhaobo | |
| dcterms.dateAccepted | 2013-05-22T17:34:30Z | |
| dcterms.dateAccepted | 2015-04-24T14:46:32Z | |
| dcterms.dateSubmitted | 2013-05-22T17:34:30Z | |
| dcterms.dateSubmitted | 2015-04-24T14:46:32Z | |
| dcterms.description | Department of
Chemistry | en_US |
| dcterms.extent | 126
pg. | en_US |
| dcterms.format | Application/PDF | en_US |
| dcterms.format | Monograph | |
| dcterms.identifier | http://hdl.handle.net/1951/59644 | |
| dcterms.identifier | Fan_grad.sunysb_0771M_10930 | en_US |
| dcterms.identifier | http://hdl.handle.net/11401/71217 | |
| dcterms.issued | 2012-05-01 | |
| dcterms.language | en_US | |
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Previous issue date: 1 | en |
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Previous issue date: 1 | en |
| dcterms.publisher | The Graduate School, Stony Brook University: Stony Brook, NY. | |
| dcterms.subject | Chemistry | |
| dcterms.title | Host-Guest Approach for 1,6-Topochemical Polymerization
of Triacetylenes | |
| dcterms.type | Thesis | |
