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dc.identifier.urihttp://hdl.handle.net/11401/76331
dc.description.sponsorshipThis work is sponsored by the Stony Brook University Graduate School in compliance with the requirements for completion of degree.en_US
dc.formatMonograph
dc.format.mediumElectronic Resourceen_US
dc.language.isoen_US
dc.publisherThe Graduate School, Stony Brook University: Stony Brook, NY.
dc.typeDissertation
dcterms.abstractEngineered Polymer hydrogels and hydrogels from Bio macromolecules have visco-elastic properties that can be measured using Oscillatory Shear Rheology. Manipulation and measurement of physical properties in gels including F-127 Pluronic Block Co-Polymer and Poly(N-isopropylacrylamide)-Clay are shown through OSR by addition of salts, clays and glucose at physiological levels. Rheological analysis of f-127 illustrates changes in G' reduction with phase transition temperature. Measurements also indicate physical changes due to the aforementioned additives vary as a function of the gel physical and chemical structure. In particular, non-enzymatic glycation is shown to change the modulus of elasticity in both of the gels tested. Rheological analysis is also interpreted to produce a reduction In gel mesh size in the PNIPA -clay gels due to a possible co-solvency between phases of varying degrees of hydration.
dcterms.available2017-09-20T16:50:02Z
dcterms.contributorGersappe, Dilipen_US
dcterms.contributorRafailovich, Miriamen_US
dcterms.contributorSokolov, Johnathanen_US
dcterms.contributorMammone, Thomas.en_US
dcterms.creatorLombardi, Jack
dcterms.dateAccepted2017-09-20T16:50:02Z
dcterms.dateSubmitted2017-09-20T16:50:02Z
dcterms.descriptionDepartment of Materials Science and Engineering.en_US
dcterms.extent63 pg.en_US
dcterms.formatMonograph
dcterms.formatApplication/PDFen_US
dcterms.identifierhttp://hdl.handle.net/11401/76331
dcterms.issued2014-12-01
dcterms.languageen_US
dcterms.provenanceMade available in DSpace on 2017-09-20T16:50:02Z (GMT). No. of bitstreams: 1 Lombardi_grad.sunysb_0771E_12192.pdf: 1807421 bytes, checksum: b7073acbe591d140a1ee315af6161c89 (MD5) Previous issue date: 1en
dcterms.publisherThe Graduate School, Stony Brook University: Stony Brook, NY.
dcterms.subjectEngineering
dcterms.subjectClay, Hydrogels, Rheology
dcterms.titleRheological Characterization of Nano Composite Hydrogels
dcterms.typeDissertation


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