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dc.identifier.urihttp://hdl.handle.net/1951/59831
dc.identifier.urihttp://hdl.handle.net/11401/71383
dc.description.sponsorshipThis work is sponsored by the Stony Brook University Graduate School in compliance with the requirements for completion of degree.en_US
dc.formatMonograph
dc.format.mediumElectronic Resourceen_US
dc.language.isoen_US
dc.publisherThe Graduate School, Stony Brook University: Stony Brook, NY.
dc.typeThesis
dcterms.abstractA polymer dead layer is a very thin interfacial layer of polymer formed at the solid substrate interface, with no thermal expansion coefficient and molecular mobility. The polymer dead layer has many unique properties compared to the bulk polymer, including the mobility of polymer chains, glass transition temperature, viscosity and so on. In this thesis, organic clay nanoparticles are used as a nanofiller to see how the properties/structures a polystyrene dead layer can be altered. To characterize the structures of PS/clay dead layers, we used ellipsometry, X-ray scattering techniques, and atomic force microscopy (AFM). In addition, supercritical carbon dioxide was used as a screening solvent to control the polymer/substrate interactions.
dcterms.available2013-05-22T17:35:26Z
dcterms.available2015-04-24T14:47:16Z
dcterms.contributorDudley, Michaelen_US
dcterms.contributorKoga, Tadanorien_US
dcterms.contributorVenkatesh, T. A..en_US
dcterms.creatorRUAN, YUXUAN
dcterms.dateAccepted2013-05-22T17:35:26Z
dcterms.dateAccepted2015-04-24T14:47:16Z
dcterms.dateSubmitted2013-05-22T17:35:26Z
dcterms.dateSubmitted2015-04-24T14:47:16Z
dcterms.descriptionDepartment of Materials Science and Engineeringen_US
dcterms.extent29 pg.en_US
dcterms.formatApplication/PDFen_US
dcterms.formatMonograph
dcterms.identifierhttp://hdl.handle.net/1951/59831
dcterms.identifierRUAN_grad.sunysb_0771M_10873en_US
dcterms.identifierhttp://hdl.handle.net/11401/71383
dcterms.issued2012-05-01
dcterms.languageen_US
dcterms.provenanceMade available in DSpace on 2013-05-22T17:35:26Z (GMT). No. of bitstreams: 1 RUAN_grad.sunysb_0771M_10873.pdf: 1753912 bytes, checksum: f6e586d923626db35de305489e57f931 (MD5) Previous issue date: 1en
dcterms.provenanceMade available in DSpace on 2015-04-24T14:47:16Z (GMT). No. of bitstreams: 3 RUAN_grad.sunysb_0771M_10873.pdf.jpg: 1894 bytes, checksum: a6009c46e6ec8251b348085684cba80d (MD5) RUAN_grad.sunysb_0771M_10873.pdf.txt: 54914 bytes, checksum: e9474edd6891c6f4fc29ada26e1cfc56 (MD5) RUAN_grad.sunysb_0771M_10873.pdf: 1753912 bytes, checksum: f6e586d923626db35de305489e57f931 (MD5) Previous issue date: 1en
dcterms.publisherThe Graduate School, Stony Brook University: Stony Brook, NY.
dcterms.subjectMaterials Science
dcterms.subjectclay, dead layer, polystyrene, scCO2, two interfacial effect
dcterms.titleThe Effect of Nanoparticles on the Properties of Polystyrene Dead Layers
dcterms.typeThesis


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